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X2D

A 2D materials platform empowered by X elemental engineering

X2D is a research platform through to garner projects on 2D materials synthesis and engineering towards nanotechnology applications. X2D emerges as an evolution of the original ERC-CoG grant XFab on the "Xene fabrication for a novel 2D nanotechnology platform" in place from April 2028 to March 2024. The XFab was then paralleled by other aggregated ERC-PoC projects, XMem (2022-23) and TNext (2024- ), concerning with the silicene membranes in flexible electronic devices and tellurene memristors, respectively. Xenes are a relatively new class of 2D elemental materials beyond graphene which includes elements from the group II to the group VI in the periodic table. X2D is more than the follow-up of an ERC project concept, and its ambition is to more generally encompass the development of 2D materials starting from the details of an individual elements. As such, it is the natural target of the past research developed on the materials engineering of transition metal dichalcogenides. In this framework, while we previously investigated the chemical vapor deposition of MoS2 by inducing directional anisotropy by design, more recently we focused on the production of MTe2 (with M=Mo, W, Pt, ...) by governing the Te chemistry during the tellurization of a pre-deposited metal film. This approach paves the way to a phase selection of the nanosheets thereby enabling us to control che electronic character, from a semiconductor (e.g. MoTe2 in the 2H phase) to a metal (e.g. MoTe2 in the 1T' phase) to a Dirac semimetallo (e.g. PtTe2). The X2D platform is so articulated in the main research directions, XFab, XMem, TNext, and MX2, as detailed below.
 

X2D
Projects

an ERC-CoG project on Xene fabrication inspiring other focused projects on specific technologies

an ERC-PoC project on the technology transfer of silicene membranes

an ERC-PoC project on the integration of tellurene in memristors

a framework encompassing the production of transition metal dichalcogenides from the single elemental components

Spotlight

Tellurium goes memristive

Christian et al. drive us into the unprecedented world of a new fashion of atomically thin membranes where silicene is electrically responsive to mechanical solicitations and strain. Now published in Advanced Materials (2023), 35, 2211419

Advanced Science - 2025 - Ghomi - Non‐Volatile Resistive Switching in Nanoscaled Elemental

News

 Symposium B, E-MRS 2025 Spring Meeting

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May 26-30, 2025

Alessandro is been organising Symposium B "Topological materials and their application to classical and quantum nanotechnologies", Abstract Submission Open up to January 28, 2025. 

Silicene by topotactic deintercalation

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December 18, 2024

With Erika Kozma from CNR-Scitec leading,  we show that silicene nanosheets can be effectively and quickly produced by topotactic deintercalation from CaSi2. See more on the paper by Kozma, Martella, et al, Small 2024.

World's Top 2% Scientists' 2024 List

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October 22, 2024

Alessandro within the 2024 World's Top 2% Scientist List released by Elsevier/Stanford University

after being included in the 2020, 2021, 2022, 2023 lists.

Memristive switching in tellurium

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October 1, 2024

Sara, Christian et al show the nanoscale tellurium display non-volatile switching behaviour in memristor cells. Ghomi et al., Advanced Science (2024), 2406703 

THz plasmon resonance from topological PtTe2 

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May 11, 2024

PtTe2 is a Dirac semimetal which can host plasmonic resonance if configured as a meta surfaces. Look at our study by Macis et al., Advanced Materials (2024), 36, 2400554  

Covers

May 26-30, 2025

Alessandro serving as co-organizer of Symposium B "Topological materials and their application to classical and quantum nanotechnologies", Abstract Submission Open up to January 28, 2025

Conferences

Open Positions

Research Grant

Topic: Nanoscale tellurium growth for memristive applications

Duration: 14 months

Call: https://www.urp.cnr.it/node/21291 (deadline: December 19, 2024)

Contact: Alessandro Molle

Status: Assigned

PhD Thesis

Topic: Molecular beam epitaxy of 2D elementary materials (Xenes)

Topic: Synthesis of interface engineered Xenes and in situ characterization (STM, Raman)

Contact: Alessandro Molle

Call for MSc Thesis

List of Topics:

  • Scanning tunneling microscopy investigation of Xenes grown by molecular beam epitaxy;

  • Molecular beam epitaxy of Xene layers and heterostructures;

  • Chemical vapor deposition of transition metal dichalcogenides for nanoelectronics;

  • Chemical vapor deposition of 2D materials for THz and far-IR applications; 

  • Processing and nanofabrication of electronic and optoelectronic devices based on 2D materials;

  • Opto-thermo-electrical, chemical and structural characterization of 2D materials.

Staff work-team: ​Carlo Grazianetti, Christian Martella, Alessio Lamperti, Alessandro Molle

Contact: Alessandro Molle

Upcoming Events

Contacts

CNR-IMM unit of Agrate Brianza,
via C. Olivetti 2, 20864 Agrate Brianza, IT

+39 0396032884

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